We hear every day from elders and parents, that waking up early is the most important thing in our life.
Each individual is different and his biology is different from another individual.
After overnight sleep, your body needs to be hydrated hence you need water first in the morning.
This makes you feel less fatigued and look fresh, washing your face with water also helps along with drinking water.
Reading a book before going to bed is a good idea, this is to avoid watching mobile or computer which actually blocks the production of melatonin.